Recent Advances in the Use of Transition-Metal Porphyrin and Phthalocyanine Complexes as Electro-Catalyst Materials on Modified Electrodes for Electroanalytical Sensing Applications
Jesús Antonio Cruz-Navarro, Fabiola Hernández-García, Luis Humberto Mendoza-Huízar, Verónica Salazar, J.A. Cobos-Murcia, Raúl Colorado‐Peralta, Giaan Arturo Álvarez‐Romero
Abstract
Metalloporphyrins (MP) and metallophtalocyanines (MPc) are innovative materials with catalytic properties that have attracted attention for their application for diverse electrochemical purposes. The presence of metallic centers in their structure offers a redox-active behavior that is being applied in the design of solid electrodes for the quantification of biomolecules, water contaminants, and pharmaceuticals, among others. Herein, we collect the recent information about porphyrin and phthalocyanine complexes as modifiers of electrodes, and the important aspects of the design, characterization, and application of these electrodes.