Litcius/Paper detail

High-Entropy 2D Carbide MXenes: TiVNbMoC <sub>3</sub> and TiVCrMoC <sub>3</sub>

Srinivasa Kartik Nemani, Bowen Zhang, Brian C. Wyatt, Zachary D. Hood, Sukriti Manna, Rasoul Khaledialidusti, Weichen Hong, Michael Sternberg, Subramanian K. R. S. Sankaranarayanan, Babak Anasori

2021ACS Nano393 citationsDOIOpen Access PDF

Abstract

., no pure single-phase forms). This finding indicates the importance of configurational entropy in stabilizing the desired single-phase high-entropy MAX over multiphases of MAX, which is essential for the synthesis of phase-pure high-entropy MXenes. The synthesis of high-entropy MXenes significantly expands the compositional variety of the MXene family to further tune their properties, including electronic, magnetic, electrochemical, catalytic, high temperature stability, and mechanical behavior.

Topics & Concepts

MXenesMaterials scienceCarbideTransition metalX-ray photoelectron spectroscopyMAX phasesEntropy (arrow of time)Phase transitionThermodynamicsChemistryNanotechnologyPhysicsNuclear magnetic resonanceComposite materialBiochemistryCatalysisMXene and MAX Phase Materials2D Materials and ApplicationsFerroelectric and Negative Capacitance Devices