Ion exchange: an essential piece in the fabrication of zeolite adsorbents
Chenxin Li, Tiesen Li, Qingyan Cui, Tinghai Wang, Chan Wang, Jiao Yang, Jie Shi, Xiaojun Bao, Yuanyuan Yue
Abstract
-paraffin and xylene isomers. Ion exchange, as an essential piece in the fabrication of zeolite-based adsorbents, significantly affects overall performance. In this review, we survey the recent key developments and issues within ion exchange research of zeolite-based adsorbents, including the solution pH, solution concentration, ion-exchange cycles, ion-exchange temperature, ion-exchange time, calcination temperature, and discuss the mechanisms of their influence on zeolite adsorption. This review also elaborates on the negative effects of improper ion exchange on incomplete cation exchange, cation migration, collapse of the zeolite structure, and blockage of zeolite pores. Other parameters that lack research but have been proven to affect ion exchange are also mentioned. We hope to generate interest in the wider community and encourage others to make use of ion exchange in tackling challenges of adsorption separation science and engineering.