[Na<sub>4</sub>(N<sub>5</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>]·H<sub>2</sub>O·2MeOH: a honeycomb-like sodium pentazolate framework with helical chains
Yuangang Xu, Ze Xu, Xiaopeng Zhang, Tianyang Hou, Ming Lu
Abstract
A new NaN 5 framework, [Na 4 (N 5 ) 4 (H 2 O) 2 ]·H 2 O·2MeOH, was synthesized. It features a UNJ-type zeolite topology with double right-handed helical chains constructing enclosed homochiral channels filled with water and methanol molecules.
Topics & Concepts
ZeoliteMethanolSodiumMoleculeHoneycombCrystallographyChemistryMaterials scienceTopology (electrical circuits)CombinatoricsCatalysisOrganic chemistryMathematicsComposite materialMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Chemistry and MaterialsCrystallography and molecular interactions