Metal-mediated tunability of MOF-based optical modulators
Nikita K. Kulachenkov, Bogdan Orlioglo, Eugene S. Vasilyev, Svyatoslav A. Povarov, Alexander M. Agafontsev, Semyon V. Bachinin, Sergei A. Shipilovskikh, Artem Lunev, Denis G. Samsonenko⧫, Vladimir P. Fedin, Konstantin A. Kovalenko, Valentin A. Milichko
Abstract
We report on the design of 1D MOFs based on a nopinane-annelated organic ligand and Co(II) or Ni(II), the variation of which allows tuning the optical modulation bandwidth. Structural and time-resolved analysis revealed the optical modulation mechanism, the rates and its endurance, thereby enriching the list of sustainable MOFs for tunable optical modulators.
Topics & Concepts
Modulation (music)Metal-organic frameworkMaterials scienceOptoelectronicsOptical modulatorOptical switchBandwidth (computing)MetalLigand (biochemistry)ChemistryTelecommunicationsPhase modulationComputer scienceReceptorPhysicsAdsorptionPhysical chemistryOrganic chemistryAcousticsMetallurgyPhase (matter)BiochemistryPorphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchMetal-Organic Frameworks: Synthesis and Applications