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A promising TNT alternative 3,3′-bi(1,2,4-oxadiazole)-5,5′-diylbis(methylene)dinitrate (BOM): thermal behaviors and eutectic characteristics

Xiong Yang, Jing Zhou, Xiaoling Xing, Yafeng Huang, Zhengfeng Yan, Qi Xue, Xiaofeng Wang, Bozhou Wang

2020RSC Advances17 citationsDOIOpen Access PDF

Abstract

FTIR technologies. The low eutectic characteristics of BOM and DNTF were also investigated carefully and the best ratio of BOM/DNTF was 40/60 with a melting point at 75.5 °C. Finally, the detonation performances of TNT/HMX, BOM/HMX and BOM/DNTF(40/60)/HMX explosive formulations were calculated, showing that the detonation performances of the latter two formulations were significantly higher than that of TNT/HMX.

Topics & Concepts

Eutectic systemThermal decompositionEnergetic materialExplosive materialThermal stabilityChemistryMethyleneDetonation velocityFourier transform infrared spectroscopyMelting pointMelting temperatureThermalDetonationMaterials scienceAnalytical Chemistry (journal)Chemical engineeringOrganic chemistryThermodynamicsComposite materialAlloyEngineeringPhysicsEnergetic Materials and CombustionThermal and Kinetic AnalysisCombustion and Detonation Processes