Right-/left-handed helical G-quartet nanostructures with full-color and energy transfer circularly polarized luminescence
Jingqi Chen, Xiaowei Liu, Zhiguang Suo, Chenqi Gao, Feifei Xing, Lingyan Feng, Chuanqi Zhao, Lianzhe Hu, Jinsong Ren, Xiaogang Qu
Abstract
Right (R)- and left (L)-handed helical G-quartet nanostructures were synthesized for the first time simultaneously via the self-assembly of 5'-guanosine monophosphate (GMP), the helical handedness of which is well regulated by metal ions. These g-nanostructures were further applied as circularly polarized luminescence (CPL) templates to realize full-color R-/L-CPL and Förster resonance energy transfer CPL. The glum value reached 10-2, indicating their excellent template function for CPL materials design and application.
Topics & Concepts
LuminescenceEnergy transferCircular polarizationNanostructureGuanosineLeft handedPhysicsMaterials scienceCrystallographyOpticsOptoelectronicsNanotechnologyChemistryAtomic physicsBiochemistryMicrostripSynthesis and Properties of Aromatic CompoundsDNA and Nucleic Acid ChemistryMetamaterials and Metasurfaces Applications