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Selective methylene oxidation in α,β-unsaturated carbonyl natural products

Chiyoung Ahn, Alexander Gomez, Marc A. Hartmann, M. Christina White

2025Nature9 citationsDOI

Topics & Concepts

ChemistryAllylic rearrangementMethyleneCatalysisSteric effectsSolventMoleculeCombinatorial chemistryConjugated systemOrganic chemistryManganeseDouble bondAlcohol oxidationPhotochemistryHydrogen bondReactive intermediateCarboxylic acidOlefin fiberSurface modificationChemoselectivityRedoxMetalCatalytic oxidationReaction mechanismOxidative Organic Chemistry ReactionsCatalysis and Oxidation ReactionsChemical Synthesis and Reactions
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