Luminescent Ir(<scp>iii</scp>)–Ln(<scp>iii</scp>) coordination polymers showing slow magnetization relaxation
Kun Fan, Song‐Song Bao, Ran Huo, Xin‐Da Huang, Yujie Liu, Zi‐Wen Yu, Mohamedally Kurmoo, Li‐Min Zheng
Abstract
Two structural types of iridium(<sc>iii</sc>)–lanthanide(<sc>iii</sc>) coordination polymers, single-chain<bold>Ir2Ln</bold>and double-chain<bold>Ir4Ln2</bold>(Ln = Gd, Dy, Er, and Yb), have been prepared. SMM behaviour and NIR luminescence were observed for the Ir–Er and Ir–Yb systems.
Topics & Concepts
LanthanideIridiumLuminescenceRelaxation (psychology)PolymerCrystallographyMaterials scienceMagnetizationChemistryIonPhysicsOrganic chemistryOptoelectronicsCatalysisSocial psychologyMagnetic fieldPsychologyQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications