Elucidating the role of non-covalent interactions in unexpectedly high and selective CO<sub>2</sub> uptake and catalytic conversion of porphyrin-based ionic organic polymers
Sinem Tuncel Kostakoğlu, Yurii Chumakov, Yunus Zorlu, Ali Enis Sadak, Serpil Denizaltı, Ayşe Gül Gürek, Mehmet Menaf Ayhan
Abstract
Here, we present viologen-porphyrin based ionic covalent organic polymers (<bold>H2-ICOP</bold> and <bold>Zn-ICOP</bold>) with multiple CO<sub>2</sub>-philic sites.
Topics & Concepts
PorphyrinCovalent bondIonic bondingCatalysisPolymerChemistryPhotochemistryCombinatorial chemistryPolymer chemistryOrganic chemistryIonCovalent Organic Framework ApplicationsCO2 Reduction Techniques and CatalystsCarbon Dioxide Capture Technologies