Rh(<scp>iii</scp>)-Catalyzed tandem C(sp<sup>2</sup>)–H allylation/<i>N</i>-alkylation annulation of arene amides with 2-alkylidenetrimethylene carbonates
Hui Xie, Jin-Yi Liang, Zhuojun Huang, Bing Shu, Yi‐Chuan Zheng, Yanzhi Liu, Shaoyong Chen, Xu‐Ge Liu, Shang‐Shi Zhang
Abstract
A Rh( iii )-catalyzed tandem C(sp 2 )–H allylation/ N -alkylation annulation reaction of arene amides employing 5-methylene-1,3-dioxan-2-one as an efficient allyl source has been disclosed for the first time.
Topics & Concepts
ChemistryAnnulationTandemAlkylationCatalysisMethyleneMedicinal chemistryStereochemistryOrganic chemistryMaterials scienceComposite materialCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsCyclopropane Reaction Mechanisms