Facet engineering of MOF supports regulates product selectivity in CO<sub>2</sub> photoreduction by modulating electron and proton supply to COF shells
Hulin Shi, Zengrong Li, Shenglan Chen, Yangtao Yao, Linyi Wu, Ruowen Shao, Chang Sheng, Shuxian Zhong, Dongmei Wang, Yuling Zhao, Leihong Zhao, Song Bai
Abstract
NH 2 -MIL-125 facets control the distribution of electrons and protons between the NH 2 -MIL-125 core for H 2 evolution and the T-COF shell for CO 2 hydrogenation, thereby determining the product selectivities of the heterojunctions in CO 2 photoreduction.
Topics & Concepts
Dissociation (chemistry)SelectivityElectronProtonFacet (psychology)PhotochemistryMaterials scienceReduction (mathematics)ChemistryNanotechnologyCatalysisOrganic chemistryPhysicsPersonalityQuantum mechanicsGeometryPsychologyMathematicsBig Five personality traitsSocial psychologyAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis