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Heavy iron in large gem diamonds traces deep subduction of serpentinized ocean floor

Evan M. Smith, Peng Ni, Steven B. Shirey, Stephen H. Richardson, Wuyi Wang, Anat Shahar

2021Science Advances41 citationsDOIOpen Access PDF

Abstract

Os = 0.111). These iron values lie outside the range of known mantle compositions or expected reaction products at depth. This signature represents subducted iron from magnetite and/or Fe-Ni alloys precipitated during serpentinization of oceanic peridotite, a lithology known to carry unradiogenic osmium inherited from prior convection and melt depletion. These diamond-hosted inclusions trace serpentinite subduction into the mantle transition zone. We propose that iron-rich phases from serpentinite contribute a labile heavy iron component to the heterogeneous convecting mantle eventually sampled by oceanic basalts.

Topics & Concepts

PeridotiteSubductionGeologyGeochemistryMantle (geology)PetrologySeismologyTectonicsGeological and Geochemical AnalysisHigh-pressure geophysics and materialsCrystal Structures and Properties