Enhancement of the optical properties of CsPbBr₃ perovskite nanocrystals using three different solvents

Abstract

Green-emitting <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">C</mml:mi> <mml:mi mathvariant="normal">s</mml:mi> <mml:mi mathvariant="normal">P</mml:mi> <mml:mi mathvariant="normal">b</mml:mi> <mml:mi mathvariant="normal">B</mml:mi> <mml:mi mathvariant="normal">r</mml:mi> </mml:mrow> </mml:mrow> <mml:mn>3</mml:mn> </mml:msub> </mml:mrow> </mml:math> perovskite nanocrystals were synthesized by the modified hot-injection method using three different solvents. The produced nanocrystals showed a narrow green emission band centered at 515–520 nm with full width at half-maximum (FWHM) values of approximately 18–20 nm. The highest photoluminescence quantum yield (PLQY) was obtained for the nanocrystal sample synthesized using a paraffin liquid solvent, with a value of 70.1% under excitation at 450 nm. The <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">C</mml:mi> <mml:mi mathvariant="normal">s</mml:mi> <mml:mi mathvariant="normal">P</mml:mi> <mml:mi mathvariant="normal">b</mml:mi> <mml:mi mathvariant="normal">B</mml:mi> <mml:mi mathvariant="normal">r</mml:mi> </mml:mrow> </mml:mrow> <mml:mn>3</mml:mn> </mml:msub> </mml:mrow> </mml:math> nanocrystals film light-emitting diodes (LED) chip module showed a luminous efficacy of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>40.7</mml:mn> </mml:mrow> <mml:mspace width="thickmathspace"/> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">l</mml:mi> <mml:mi mathvariant="normal">m</mml:mi> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo>/</mml:mo> </mml:mrow> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">W</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">r</mml:mi> <mml:mi mathvariant="normal">a</mml:mi> <mml:mi mathvariant="normal">d</mml:mi> </mml:mrow> </mml:mrow> </mml:msub> </mml:mrow> </mml:math> . The white LED (WLED) with green <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">C</mml:mi> <mml:mi mathvariant="normal">s</mml:mi> <mml:mi mathvariant="normal">P</mml:mi> <mml:mi mathvariant="normal">b</mml:mi> <mml:mi mathvariant="normal">B</mml:mi> <mml:mi mathvariant="normal">r</mml:mi> </mml:mrow> </mml:mrow> <mml:mn>3</mml:mn> </mml:msub> </mml:mrow> </mml:math> and red <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">C</mml:mi> <mml:mi mathvariant="normal">s</mml:mi> <mml:mi mathvariant="normal">P</mml:mi> <mml:mi mathvariant="normal">b</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">I</mml:mi> </mml:mrow> </mml:mrow> <mml:mn>3</mml:mn> </mml:msub> </mml:mrow> </mml:math> nanocrystal films emitted bluish-white light with a high color rendering index of 89, and the luminous efficacy of the WLED reached <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>16.3</mml:mn> </mml:mrow> <mml:mspace width="thickmathspace"/> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">l</mml:mi> <mml:mi mathvariant="normal">m</mml:mi> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo>/</mml:mo> </mml:mrow> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">W</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">r</mml:mi> <mml:mi mathvariant="normal">a</mml:mi> <mml:mi mathvariant="normal">d</mml:mi> </mml:mrow> </mml:mrow> </mml:msub> </mml:mrow> </mml:math> .

Topics & Concepts