Direct synthesis of a stable radical doped electrically conductive coordination polymer
Yong Yan, Ningning Zhang, Lisa Marie Tauche, Kavipriya Thangavel, Andreas Pöppl, Harald Krautscheid
Abstract
K-ONDI, a directly synthesized coordination polymer, contains NDI˙ − radicals that are stable in air and in common organic solvents. Benefiting from π–π interactions and unpaired electrons, K-ONDI exhibits an electrical conductivity of 10 −6 S cm −1 .
Topics & Concepts
Unpaired electronRadicalPolymerElectrical conductorDopingCoordination polymerElectrical resistivity and conductivityMaterials scienceConductivityPolymer chemistryElectronCoordination complexPhotochemistryMetalChemistryOrganic chemistryPhysical chemistryOptoelectronicsComposite materialMetallurgyPhysicsElectrical engineeringEngineeringQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchConducting polymers and applications