Litcius/Paper detail

Intra- and intermolecular interception of a photochemically generated terminal uranium nitride

Munendra Yadav, Alejandro J. Metta‐Magaña, Skye Fortier

2020Chemical Science45 citationsDOIOpen Access PDF

Abstract

Photolysis of the U( <sc>iv</sc> ) azide L <sup>Ar</sup> U(NIm <sup>Dipp</sup> ) generates a reactive uranium nitride intermediate that can be intercepted by nucleophilic substrates – the first example of intermolecular chemistry of a rare photochemically generated uranium nitride.

Topics & Concepts

NitrideUraniumIntermolecular forcePhotodissociationChemistryNucleophileAzidePhotochemistryInterceptionMoleculePhysicsOrganic chemistryNuclear physicsCatalysisLayer (electronics)EcologyBiologyRadioactive element chemistry and processingRadioactive contamination and transferRadiopharmaceutical Chemistry and Applications