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Design of selective divalent chain transfer agents for coordinative chain transfer polymerization of ethylene and its copolymerization with butadiene

Nicolas Baulu, Marie-Noëlle Poradowski, Ludmilla Verrieux, Julien Thuilliez, F. Jean-Baptiste-Dit-Dominique, Lionel Perrin, Franck D’Agosto, Christophe Boisson

2022Polymer Chemistry16 citationsDOIOpen Access PDF

Abstract

A selective divalent chain transfer agent is designed to exclusively lead to polyolefin chain growth on a divalent pentanediyl moiety via coordinative chain transfer polymerization (CCTP).

Topics & Concepts

CopolymerChain transferEthyleneChain (unit)Polymer chemistryPolymerizationLiving polymerizationDivalentChemistryMaterials sciencePolymerRadical polymerizationOrganic chemistryCatalysisPhysicsAstronomyAdvanced Polymer Synthesis and CharacterizationGreen IT and SustainabilityFiber-reinforced polymer composites
Design of selective divalent chain transfer agents for coordinative chain transfer polymerization of ethylene and its copolymerization with butadiene | Litcius