Stable and Flexible Polyurethane Membranes with WO<sub>3</sub>/Bi<sub>2</sub>MoO<sub>6</sub> Nanoparticles for the Photocatalytic Degradation of 2,4-Dichlorophenol
Huining Zhang, Yuling Tang, Yang Cao, Jianping Han, Shaofeng Wang, Lihong Tian, Zhongyu Shi, Zongqian Zhang, Zhiqiang Wei, Zhiguo Wu, Ying Zhu, Qi Guo
Abstract
The objective of this work is to develop a microsomal composite catalytic membrane that exhibits efficient catalytic capabilities and robust stability, thereby addressing the challenge of recycling and reusing powdered photocatalytic materials. Specifically, Bi 2 MoO 6 and WO 3 nanoparticles were incorporated onto polyurethane (PU) substrates using a hybrid in situ growth method. By forming Bi 2 MoO 6 /WO 3 heterojunctions, the photocatalytic activity of the membrane was enhanced without compromising its structural integrity. The flexibility and porosity of PUs play a crucial role in facilitating the adsorption of 2,4-dichlorophenol (DCP) molecules on the membrane’s surface, leading to the efficient degradation of contaminants through the cleavage of C–Cl bonds triggered by the migration of electron pairs generated by the photocatalysts. A 5 × 5 cm composite membrane was tested for degradation in 20 mg/L 2,4-DCP solutions with neutral pH, achieving a degradation rate of 78.8% within 120 min. The composite membrane exhibited stability after undergoing six cycles of testing, affirming the effectiveness of its composition. Furthermore, a detailed analysis was conducted on the photocatalytic reaction mechanism of 2,4-DCP on the WO 3 /Bi 2 MoO 6 /PU membrane surface, highlighting the potential of porous composite membranes for wastewater treatment.