Trapping a [W<sub>10</sub>O<sub>32</sub>]<sup>6−</sup> Decatungstate Anion in an Ag<sub>44</sub> Nanowheel
Jia‐Qun Yu, Chun‐Hui Xue, Kun Zhou, Yuan Fang, Jiu‐Yu Ji, Baokuan Chen, Yanfeng Bi
Abstract
Abstract Compound [Ag 44 (W 10 O 32 )(S t Bu) 24 (CF 3 COO) 8 ](CF 3 COO) 6 ⋅ 6H 2 O ( 1 ) was synthesized through a one‐pot method. This is the first case of isolating a new silver thiolate cluster containing a [W 10 O 32 ] 6− template which transforms from WO 4 2− polyoxoanion through a self‐assembly process. The anionic nature of the reduced [W 10 O 32 ] 6− template and the effective silver‐oxygen interaction contribute to the formation of the Ag 44 nanowheel in 1 . The luminescence, photocatalytic activity and electrochemistry properties of 1 were studied.
Topics & Concepts
IonCluster (spacecraft)LuminescenceElectrochemistryChemistryPolyoxometalateTrappingOxygenOxygen atomCrystallographyInorganic chemistryMaterials sciencePhysical chemistryElectrodeMoleculeCatalysisOptoelectronicsOrganic chemistryBiologyComputer scienceEcologyProgramming languageNanocluster Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis