Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation
Degang Ke, Sheng‐Li Huang, Guo‐Yu Yang
Abstract
Three polyoxometalate-based metal–organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)3]2+ photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity. The reactive oxygen species as well as the photooxidation mechanism were also explored.
Topics & Concepts
PolyoxometalateChemistryLanthanideSulfidePhotocatalysisPhotochemistrySelectivityPhotosensitizerInorganic chemistrySulfoxideMetalMetal-organic frameworkIonCatalysisOrganic chemistryAdsorptionPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Reactions