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Modulating paired Ir–O–Ir <i>via</i> electronic perturbations of correlated Ir single atoms to overcome catalytic selectivity

Shi‐Hua Chen, Yuan‐Fan Yang, Zong‐Yin Song, Xiang‐Yu Xiao, Congcong Huang, Xin Cai, Pei‐Hua Li, Meng Yang, Aicheng Chen, Wenqing Liu, Xing‐Jiu Huang

2023Chemical Science25 citationsDOIOpen Access PDF

Abstract

, thus exhibiting superior selectivity for As(iii) in contrast to other common heavy metal cations. This work offers useful insights into the rational design of intriguing SACs with high selectivity and stability for the electrocatalysis and electrochemical analysis of pollutants on an electronic level.

Topics & Concepts

ElectrocatalystMetalCatalysisChemistrySelectivityAtom (system on chip)Electronic structureInfrared spectroscopyCrystallographyPhysical chemistryComputational chemistryElectrochemistryElectrodeOrganic chemistryEmbedded systemComputer scienceBiochemistryElectrocatalysts for Energy ConversionElectrochemical Analysis and ApplicationsAdvancements in Battery Materials
Modulating paired Ir–O–Ir <i>via</i> electronic perturbations of correlated Ir single atoms to overcome catalytic selectivity | Litcius