Decomposition of triazole and 3-nitrotriazole upon low-energy electron attachment
Muhammad Saqib, Farhad Izadi, Leon U. Isierhienrhien, Milan Ončák, Stephan Denifl
Abstract
or the release of an OH radical), the main dissociation channel for the 3NTR anion turned out to be the direct dissociation of a hydrogen radical by a single bond cleavage, which we also observed for TR as the main channel. Thus, the triazole ring shows a pronounced stability against electron attachment-induced cleavage compared, for example, to the imidazole ring, which is found in common nitroimidazolic radiosensitizers.
Topics & Concepts
ElectronExcitationRing (chemistry)DecompositionMoleculeTriazoleLow energyChemistryChemical physicsAtomic physicsMaterials sciencePhysicsOrganic chemistryNuclear physicsQuantum mechanicsMolecular Junctions and NanostructuresSynthesis and Biological EvaluationClick Chemistry and Applications