Litcius/Paper detail

Construction of polysubstituted spiro[2.3] or [3.3] cyclic frameworks fused with a tosylated pyrrolidine promoted by visible-light-induced photosensitization

Xin-Tao Gu, Yin Wei, Min Shi

2021Organic Chemistry Frontiers13 citationsDOI

Abstract

A novel visible-light-induced intramolecular [2 + 2] cycloaddition of methylenecyclopropanes (MCPs) for the rapid construction of polysubstituted spiro[2.3] or [3.3] cyclic frameworks fused with a tosylated pyrrolidine.

Topics & Concepts

PyrrolidineIntramolecular forceChemistryCycloadditionMedicinal chemistryPhotochemistryStereochemistryCatalysisOrganic chemistryRadical Photochemical ReactionsCyclopropane Reaction MechanismsOxidative Organic Chemistry Reactions