The highly sensitive ethanol sensor based on nanocomposites of ZnO <i>in situ</i> grown on 2D Ti<sub>3</sub>C<sub>2</sub>T<i> <sub>x</sub> </i> nanosheet
Xiangrui Bu, Qiang Wu, Yubin Yuan, Haiyang Wu, Weihua Liu, Xin Li, Chuanyu Han
Abstract
Abstract Ethanol is a harmful volatile organic compound (VOC) for human health. Currently, zinc oxide (ZnO) is one of the most popular metal oxide semiconductors for VOCs detection but suffering from a lack of selectivity, poor response, and slow response/recovery speeds. Herein, we successfully synthesized the ZnO/Ti 3 C 2 T x nanocomposites via a facile hydrothermal method, in which ZnO nanoparticles were uniformly grown on two-dimensional (2D) Ti 3 C 2 T x nanosheets. As a result, the ZnO/Ti 3 C 2 T x nanocomposites showed a significant improvement in the ethanol-sensing performance, when it compared to the pure ZnO and Ti 3 C 2 T x samples. In particular, ZnO doped with 5 mg of Ti 3 C 2 T x showed an ultra-high response (79) to 100 ppm ethanol, a short response/recovery time (22 s/34 s to 50 ppm ethanol), a low limit of detection (1 ppm) and a long-term stability. The excellent ethanol sensing properties are mainly attributed to the coupling effect between ZnO and Ti 3 C 2 T x of composites. The ZnO nanoparticles are uniformly distributed on the 2D Ti 3 C 2 T x platform, which can provide more gas adsorption sites. Simultaneously, the presence of hybrid heterojunctions further enhances the response in the sensing process.