Recent Advances in Crystalline Oxidopolyborate Complexes of d-Block or p-Block Metals: Structural Aspects, Syntheses, and Physical Properties
Shu-Sheng Xin, Minghua Zhou, Michael A. Beckett, Chun‐Yang Pan
Abstract
Crystalline materials containing hybrid inorganic–organic metal borates (complexes with oxidoborate ligands) display a variety of novel framework building blocks. The structural aspects of these hybrid metallaoxidoborates containing Cd(II), Co(II), Cu(II), Ga(III), In(III), Mn(II), Ni(II) or Zn(II) metal centers are discussed in this review. The review describes synthetic approaches to these hybrid materials, their physical properties, their spectroscopic properties and their potential applications.
Topics & Concepts
Hybrid materialBlock (permutation group theory)Materials scienceMetalBoronNanotechnologyChemistryCombinatorial chemistryInorganic chemistryMetallurgyOrganic chemistryMathematicsGeometryMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications