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Emergent Inflation of the Efimov Spectrum under Three-Body Spin-Exchange Interactions

J. van de Kraats, D. J. M. Ahmed-Braun, Jing-Lun Li, S. J. J. M. F. Kokkelmans

2024Physical Review Letters11 citationsDOIOpen Access PDF

Abstract

We resolve the unexpected and long-standing disagreement between experiment and theory in the Efimovian three-body spectrum of ^{7}Li, commonly referred to as the lithium few-body puzzle. Our results show that the discrepancy arises out of the presence of strong nonuniversal three-body spin-exchange interactions, which enact an effective inflation of the universal Efimov spectrum. This conclusion is obtained from a thorough numerical solution of the quantum mechanical three-body problem, including precise interatomic interactions and all spin degrees of freedom for three alkali-metal atoms. Our results show excellent agreement with the experimental data regarding both the Efimov spectrum and the absolute rate constants of three-body recombination, and in addition reveal a general product propensity for such triatomic reactions in the Paschen-Back regime, stemming from Wigner's spin conservation rule.

Topics & Concepts

PhysicsTriatomic moleculeSpin (aerodynamics)Spectrum (functional analysis)Quantum mechanicsQuantumAtomic physicsMoleculeThermodynamicsCold Atom Physics and Bose-Einstein CondensatesAtomic and Subatomic Physics ResearchQuantum, superfluid, helium dynamics
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