Copper nanoparticles supported on highly nitrogen-rich covalent organic polymers as heterogeneous catalysts for the<i>ipso</i>-hydroxylation of phenyl boronic acid to phenol
Velu Sadhasivam, Muniyasamy Harikrishnan, Ganesan Elamathi, Rajendran Balasaravanan, S. Murugesan, Ayyanar Siva
Abstract
Here, we report the synthesis of highly nitrogen-rich covalent organic polymers as a solid heterogeneous catalyst for the oxidation of phenylboronic acid under atmospheric conditions in an aqueous medium to achieve very good yields up to 99%.
Topics & Concepts
ChemistryPhenylboronic acidBoronic acidHydroxylationCatalysisCovalent bondPhenolNitrogenOrganic chemistryNanoparticleAqueous solutionPolymerCopperPolymer chemistryChemical engineeringEngineeringEnzymeCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent Materials