Topological Design of Unprecedented Metal‐Organic Frameworks Featuring Multiple Anion Functionalities and Hierarchical Porosity for Benchmark Acetylene Separation
Yuanbin Zhang, Wanqi Sun, Binquan Luan, Jiahao Li, Dong Luo, Yunjia Jiang, Lingyao Wang, Banglin Chen
Abstract
Abstract Separation of acetylene (C 2 H 2 ) from carbon dioxide (CO 2 ) or ethylene (C 2 H 4 ) is industrially important but still challenging so far. Herein, we developed two novel robust metal organic frameworks AlFSIX‐Cu‐TPBDA (ZNU‐8) with znv topology and SIFSIX‐Cu‐TPBDA (ZNU‐9) with wly topology for efficient capture of C 2 H 2 from CO 2 and C 2 H 4 . Both ZNU‐8 and ZNU‐9 feature multiple anion functionalities and hierarchical porosity. Notably, ZNU‐9 with more anionic binding sites and three distinct cages displays both an extremely large C 2 H 2 capacity (7.94 mmol/g) and a high C 2 H 2 /CO 2 (10.3) or C 2 H 2 /C 2 H 4 (11.6) selectivity. The calculated capacity of C 2 H 2 per anion (4.94 mol/mol at 1 bar) is the highest among all the anion pillared metal organic frameworks. Theoretical calculation indicated that the strong cooperative hydrogen bonds exist between acetylene and the pillared SiF 6 2− anions in the confined cavity, which is further confirmed by in situ IR spectra. The practical separation performance was explicitly demonstrated by dynamic breakthrough experiments with equimolar C 2 H 2 /CO 2 mixtures and 1/99 C 2 H 2 /C 2 H 4 mixtures under various conditions with excellent recyclability and benchmark productivity of pure C 2 H 2 (5.13 mmol/g) or C 2 H 4 (48.57 mmol/g).