Building <i>N</i>-hydroxyphthalimide organocatalytic sites into a covalent organic framework for metal-free and selective oxidation of silanes
Man Wang, Tao Fan, Lei Fang, Gaozhang Gou, Ying Yin, Mingxian Liu, Liangchun Li
Abstract
A novel covalent organic framework orderly embedding N -hydroxyphthalimide units as organocatalytic sites was synthesized to establish a metal-free, highly selective and efficient heterogeneous system for the oxidation of various silanes to silanols.
Topics & Concepts
SilanesCovalent bondChemistryOrganocatalysisMetalOrganic chemistryCatalysisCombinatorial chemistryEnantioselective synthesisSilaneCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsPerovskite Materials and Applications