Litcius/Paper detail

PBF-LB of large-area magnesium WE43 structures surface-enhanced by plasma electrolytic oxidation

Arvid Abel, Anutsek Sharma, Hannes Holländer, Dawn Zheng, Nicole Emminghaus, Anna Buling, Jörg Hermsdorf, Jörg Zerrer, Stefan Kaierle

2024Progress in Additive Manufacturing10 citationsDOIOpen Access PDF

Abstract

Abstract Due to the improved understanding of the industry, additive manufacturing processes are becoming increasingly accepted for fabricating complex lightweight components. The focus of the magnesium research is primarily on small implant structures. Due to challenges in the manufacturing process and oxidation behavior, large structures for lightweight components are mainly fabricated with titanium. This paper expands the scope of the laser-based powder bed fusion (PBF-LB) of larger-area magnesium parts with surface enhancement using the Ultraceramic® by the plasma electrolytic oxidation (PEO). For this purpose, the PBF-LB process development for cylindric structures with a diameter of 31 mm is carried out. The processing strategies are adapted for a crack and porosity free process. To mitigate the inherent oxidation of the biodegradable WE43 and reduce the surface wear in tribologically challenging applications, the additively manufactured magnesium is modified by the Ultraceramic®. The thickness of the ceramic surface could be tailored between 10 and 40 µm, while enclosing adhering powder particles of the PBF. Electrochemical impedance spectroscopy showed an increased resistance to corrosion by an increased modulus | Z 0.01 | by a factor of 658. The tribological behavior was characterized in pin-on-disc experiments and showed a decrease of surface wear down to 7.9 × 10 –6 mm 3 /N·m up to a Hertzian pressure of 720 MPa tested by a tungsten carbide ball. Therefore, the synthesis of the PBF-LB of large-area magnesium parts and the PEO of the Ultraceramic ® enables lightweight components for challenging oxidative and tribological conditions in real world applications.

Topics & Concepts

Plasma electrolytic oxidationMagnesiumElectrolytePlasmaMetallurgyMaterials scienceMagnesium alloyChemical engineeringChemistryEngineeringPhysicsElectrodePhysical chemistryQuantum mechanicsMagnesium Alloys: Properties and ApplicationsCorrosion Behavior and InhibitionMetal and Thin Film Mechanics