Rhodium-catalyzed C–H activation/cyclization of aryl sulfoximines with iodonium ylides towards polycyclic 1,2-benzothiazines
Gao Huang, Yujia Shan, Jin‐Tao Yu, Changduo Pan
Abstract
-aryl sulfoximines with iodonium ylides was developed for the first time. In this report, C-H and N-H bond functionalization was realized towards a series of tricyclic and tetracyclic sulfoximine derivatives with moderate to excellent yields under simple reaction conditions.
Topics & Concepts
RhodiumArylChemistryCatalysisBenzothiazineTricyclicMedicinal chemistrySurface modificationCombinatorial chemistryStereochemistryOrganic chemistryAlkylPhysical chemistryCatalytic C–H Functionalization MethodsSynthesis and Catalytic ReactionsCyclopropane Reaction Mechanisms