Two new Cu-based borate catalysts with cubic supramolecular cages for efficient catalytic hydrogen evolution

Abstract

], and the atomic radius of the counter cation would be the critical factor of the photocatalytic activity. Increasing the atomic radius from the Na atom to the Rb atom, causes the photocatalytic activity to decrease efficiently. The experimental results match well with the density functional theory (DFT) conclusion. It is noteworthy to mention that our research not only enriches the Cu-based borate chemistry, but also investigates the photocatalytic activity of Cu-based borates. This would guide us through the borate synthesis and to develop their applications toward energy and the environment.

Topics & Concepts