Ideal trigonal prismatic coordination geometry of Co(<scp>ii</scp>) in a honeycomb MOF with a triptycene-based ligand
Yoshiaki Shuku, Rie Suizu, Masahisa Tsuchiizu, Kunio Awaga
Abstract
An ideal trigonal prismatic coordination geometry was achieved in the honeycomb metal–organic framework comprised of Co ions and triptycene-based bridging ligands.
Topics & Concepts
Coordination geometryTrigonal prismatic molecular geometryCrystallographyTriptyceneChemistryTrigonal crystal systemGeometryIonLigand (biochemistry)CobaltTrigonal pyramidal molecular geometryAnisotropyCrystal structureInorganic chemistryPolymer chemistryPhysicsMoleculeOctahedronReceptorQuantum mechanicsHydrogen bondBiochemistryMathematicsOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesAdvanced NMR Techniques and Applications