Litcius/Paper detail

Atomic-scale engineering of Fe–Cu nanoparticles on amine-functionalized silica: CNT-driven synergy for ultra-efficient hydrogen evolution

Nezar H. Khdary, Ekram H. El‐Ads, Ahmed Galal, Ahmad Fallatah, Sami D. Alzahrain, Muteb F Alotaibi, Mohammed J. Alotaibi

2025RSC Advances5 citationsDOIOpen Access PDF

Abstract

and an overpotential reduction of 120 mV against bare CNTs. Fe-Cu electronic interactions and CNT-mediated mass transport resulted in a 4.3-fold increase in exchange current density that the catalyst achieved relative to its monometallic counterparts. This work presents a transforming solution for scalable green hydrogen generation using a creative dual-engineering approach, molecular-scale metal anchoring, and a nano-architecture conductive support, thus solving major obstacles in catalyst durability and activity.

Topics & Concepts

Tafel equationOverpotentialMaterials scienceNanoparticleCatalysisChemical engineeringNanotechnologyExchange current densityElectrolyteHydrogen productionElectrochemistryCarbon nanotubeWater splittingHydrogenElectrolysis of waterSurface modificationNanomaterial-based catalystElectrochemical energy conversionMetalNanoelectronicsElectrocatalystElectrical conductorConductivityElectron transferCarbon fibersElectrophoretic depositionElectrocatalysts for Energy ConversionNanomaterials for catalytic reactionsAsymmetric Hydrogenation and Catalysis