Preparation of Highly Energetic Coordination Compounds with Rich Oxidants and Lower Sensitivity Based on Methyl Groups
Meiqi Xu, Tingwei Wang, Chao Zhang, Bao-long Kuang, Zhi-ming Xie, Zhenxin Yi, Zujia Lu, Yan Li, Shunguan Zhu, Jianguo Zhang
Abstract
Revamping the structure of energy storage is an efficient strategy for striking a balance between the performance and sensitivity of energetic materials to achieve high energy and reduced sensitivity. In continuation of prior research, this study utilized the ligand 3,5-dimethyl-1 H -pyrazole-4-carbonhydrazide ( DMPZCA ) and innovatively designed and synthesized the compound ECCs [Cu(HDMPZCA) 2 (ClO 4 ) 2 ](ClO 4 ) 2 ·2H 2 O ( ECCs-1 ·2H 2 O). Compared with the former research, solvent-free compound ECCs-1 refers to an innovative material characterized by a dual structure involving ionic salts and coordination compounds. Due to these unique structures, ECCs-1 exhibits an increased [ClO 4 – ] content, a higher oxygen balance constant (OB = −7.9%), and improved mechanical sensitivity (IS = 8 J, FS = 32 N). Theoretical calculations support the superior detonation performance of ECCs-1. Additionally, experimental results confirm its ignition capability through lower-threshold lasers and highlight the outstanding initiation potential and explosive power, making it a suitable candidate for primary explosives.