Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate
Natalia S. Soldatova, Amirbek D. Radzhabov, Daniil M. Ivanov, Sergi Burguera, Antonio Frontera, Pavel A. Abramov⧫, Павел С. Постников, Vadim Yu. Kukushkin
Abstract
-C plane of an iodonium cation and this geometry diverge from the IUPAC criteria for the identification of the halogen bond.
Topics & Concepts
Lock (firearm)HalogenTetragonal crystal systemCrystallographyChemistryKey (lock)StereochemistryCrystal structureOrganic chemistryComputer scienceEngineeringStructural engineeringAlkylComputer securityOxidative Organic Chemistry ReactionsVanadium and Halogenation ChemistryCrystallography and molecular interactions