Direct Stereodivergent Olefination of Carbonyl Compounds with Sulfur Ylides
Jérémy Merad, Phillip Grant, Tobias Stopka, Juliette Sabbatani, Ricardo Meyrelles, Alexander Preinfalk, J. Matyašovský, Boris Maryasin, Leticia González, Nuno Maulide
Abstract
-alkenes. In-depth computational and experimental studies clarified the mechanistic details of this unusual reactivity.
Topics & Concepts
ChemistryReactivity (psychology)StereoselectivitySulfurReagentOrganic chemistryScope (computer science)Substrate (aquarium)YlideCombinatorial chemistryCatalysisGeologyPathologyMedicineComputer scienceOceanographyAlternative medicineProgramming languageSynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques