Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution
Aijun Zhang, Miaomiao Li, Lei Guo, Huihui Yang, Jiefei Guo, Da Xu, Wei Ding
Abstract
A highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.
Topics & Concepts
ChemistryAllylic rearrangementCatalysisPhotochemistryHydrogenOrganic chemistryMetalloenzymes and iron-sulfur proteinsChemical Reactions and IsotopesEpigenetics and DNA Methylation