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First-row transition metal carbide nanosheets as high-performance cathode materials for lithium–sulfur batteries

Imran Muhammad, Shehzad Ahmed, Zhen Yao, Danish Khan, Tanveer Hussain, Yang‐Gang Wang

2023Nanoscale15 citationsDOI

Abstract

molecular dynamics simulations for lithiated polysulfide species anchored on a TMC-based model with a liquid-electrolyte medium. The microscopic reaction mechanism, revealed by the evolution of the reaction voltage during lithiation, demonstrates that the dissolution of high-order lithium-polysulfides in the electrolytes can be prevented due to their robust interaction with TMC-based cathode materials. These appealing features suggest that TMCs present colossal performance improvements for anchoring lithium-polysulfides, stimulating the active design of sulfur cathodes for practical Li-S batteries.

Topics & Concepts

Materials scienceCathodeLithium (medication)SulfurTransition metalLithium metalCarbideMetalLithium–sulfur batteryNanotechnologyInorganic chemistryMetallurgyChemistryElectrolytePhysical chemistryOrganic chemistryElectrodeEndocrinologyMedicineCatalysisAdvancements in Battery MaterialsAdvanced Battery Materials and TechnologiesInorganic Chemistry and Materials
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