Luminescent MOFs for selective sensing of Ag<sup>+</sup> and other ions (Fe(<scp>iii</scp>) and Cr(<scp>vi</scp>)) in aqueous solution
Juan‐Juan Shao, Jian-Ling Ni, Liang Yu, Guangjun Li, Li-Zhuang Chen, Fang‐Ming Wang
Abstract
Two metal–organic frameworks, [Zn(BTA) 2 ] n ( LMOF- 1), [Zn 3 (BTA) 2 (5-tbuip) 2 ] n ( LMOF- 2) (BTA = 1 H -benzotriazole, 5-tbuip = 5- tert -butylisophthalic acid) have been solvothermally synthesized. They show strong blue luminescence and LMOF- 1 shows unusually detecting behavior to Ag + .
Topics & Concepts
BenzotriazoleLuminescenceAqueous solutionChemistryIonNuclear chemistryMetalInorganic chemistryMetal ions in aqueous solutionMaterials sciencePhysical chemistryOrganic chemistryOptoelectronicsMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionMagnetism in coordination complexes