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Doping-dependent character and possible magnetic ordering of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>NdNiO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>

Frank Lechermann

2021Physical Review Materials49 citationsDOIOpen Access PDF

Abstract

The novel nickelate superconductors of infinite-layer type feature challenging electronic pecularities in the normal-state phase diagram with doping. Distinct many-body behavior and different dispersion regimes of the entangled ${\mathrm{Ni}\text{\ensuremath{-}}{d}_{{z}^{2}}$, Ni-${d}_{{x}^{2}\ensuremath{-}{y}^{2}}}$ orbital sector give rise to highly rich physics, which is here studied for the case of the $\mathrm{Nd}\mathrm{Ni}{\mathrm{O}}_{2}$ system. An analysis based on advanced realistic dynamical mean-field theory unveils that the superconducting hole-doped region is the meeting place of a (self-)doped Mott insulator from the underdoped side, and a bad Hund metal from the overdoped side. Fermi-level crossing of the Ni-${d}_{{z}^{2}}$ flat-band ties both regimes together to form a singular arena for unconventional superconductivity. We furthermore shed light on the intriguing problem of elusive magnetism in infinite-layer nickelates. Antiferromagnetic (AFM) order with small Ni moments is shown to be a vital competitor at low temperature. At stoichiometry, C-AFM order with ferromagnetic spin-alignment along the $c$-axis benefits from a conceivable coexistence with Kondo(-lattice) screening.

Topics & Concepts

AntiferromagnetismCondensed matter physicsMagnetismSuperconductivityFerromagnetismPhase diagramCharacter (mathematics)Mott insulatorMaterials scienceOrder (exchange)Phase (matter)DipoleMagnetic momentPhysicsTheoretical physicsDispersion (optics)Insulator (electricity)Electronic structureStrongly correlated materialType (biology)Reciprocity (cultural anthropology)Electronic systemsMagnetic dipoleMagnetic and transport properties of perovskites and related materialsPhysics of Superconductivity and MagnetismChemical and Physical Properties of Materials
Doping-dependent character and possible magnetic ordering of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>NdNiO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math> | Litcius