Selecting optimal R<sub>6</sub>TX<sub>2</sub> intermetallics (R = Gd, Tb, Dy; T = Mn, Fe, Co, Ni; X = Sb, Te) for magnetic refrigeration
A. Herrero, I. R. Aseguinolaza, A. Oleaga, Ángel J. García-Adeva, E. Apiñaniz, А.В. Гаршев, V. O. Yapaskurt, A.V. Morozkin
Abstract
values are in the range of 0.59-0.90, indicating a deviation from theoretical models as a reflection of the magnetic complexity in these compounds. The critical exponents have been used to confirm the scaling relations of magnetocaloric properties, and the scaling of refrigerant capacity (RC) values in materials exhibiting two magnetic phase transitions is addressed, concluding that for a correct scaling of RC the magnetic entropy change peak must be considered symmetric. The role of each atom in the properties of the compounds is discussed.
Topics & Concepts
Magnetic refrigerationIntermetallicParamagnetismMaterials scienceAtmospheric temperature rangeHeat capacityFerromagnetismCondensed matter physicsThermal conductivityThermodynamicsThermal diffusivityMagnetic fieldMagnetizationAnalytical Chemistry (journal)ChemistryMetallurgyPhysicsAlloyComposite materialQuantum mechanicsChromatographyMagnetic and transport properties of perovskites and related materialsMagnetic Properties of AlloysRare-earth and actinide compounds