Construction of σ-Aromatic AlB<sub>2</sub>Ring via Borane Coupling with a Dicoordinate Cyclic (Alkyl)(Amino)Aluminyl Anion
Kota Koshino, Rei Kinjo
Abstract
bond but also the ambiphilic nature allows for oxidative addition of Si-H, N-H, and even C-C bonds at the aluminum center.
Topics & Concepts
ChemistryBoraneAlkylRing (chemistry)NucleophileLone pairMedicinal chemistryIonElectron deficiencyComputational chemistryStereochemistryCrystallographyOrganic chemistryMoleculeCatalysisN-Heterocyclic Carbenes in Organic and Inorganic ChemistryOrganoboron and organosilicon chemistrySynthesis and characterization of novel inorganic/organometallic compounds