Cationic coordination polymers with thirteen-fold interpenetrating dia networks: selective coloration and ion-controlled photochromism
Xin Li, Yanger Li, Xiaoman Yang, Chaoyue Yan, Kai Zhang, Xiao‐Xiao Liang, Jinli Zhang, Yanli Gai, Kecai Xiong
Abstract
A novel Cd-based cationic coordination polymer (Cd-CCP) constructed using viologen derivatives, which exhibits an unusual thirteen-fold interpenetrating diamondoid network, has been synthesized. Notably, Cd-CCP displays selective and naked-eye distinguished coloration and ion-controlled photochromism towards halide anions.
Topics & Concepts
Cationic polymerizationDiamondoidPhotochromismViologenChemistryIonHalidePolymerPolymer chemistryCoordination polymerPhotochemistryInorganic chemistryMoleculeOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsPhotochromic and Fluorescence ChemistryLuminescence and Fluorescent Materials