Fabrication of Dual Self-Healing Multifunctional Coating Based on Multicompartment Microcapsules
Changyue Xu, Zhuo Chen, Chaoxia Wang, Kunlin Chen
Abstract
By designing and preparing multifunctional materials exhibiting self-healing ability, problems related to their durability outdoors can be solved. This study, inspired by the self-healing mechanism of natural creatures, successfully prepared a dual self-healing multifunctional coating using temperature stimuli-responsive multicompartment microcapsules. Phase change materials (PCMs) were employed to load multicompartment microcapsules that were produced through Pickering emulsion polymerization by applying hydrophobic materials encapsulated by titanium dioxide (TiO2) nanocapsules as Pickering emulsifiers. The multifunctional coating produced using microcapsules and self-healing waterborne polyurethane (WPU) exhibited thermal insulation and antireflection properties, which was attributed to the application of PCMs and TiO2, and it also achieved remarkable superhydrophobicity. Moreover, this coating exhibited the intrinsic and superficial dual self-healing ability, which was attributed to the release of hydrophobic materials from microcapsules and the self-healing ability of WPU. This study can be referenced to guide the fabrication of high-performance self-healing materials, and it can contribute to the long-term use of multifunctional coatings.