Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO<sub>2</sub>capture
Zhaoqiang Zhang, Qi Ding, Shing Bo Peh, Dan Zhao, Jiyu Cui, Xili Cui, Huabin Xing
Abstract
An ultramicroporous MOF, ZU-36-Ni (GeFSIX-3-Ni) is obtained for the first time via a mechanochemical-assisted approach. The material exhibits excellent performance for trace CO2 capture (1.07 mmol g-1 at 400 ppm) and benchmark 50/50 CO2/CH4 selectivity of 930, which is proven by dynamic breakthrough tests.
Topics & Concepts
TRACE (psycholinguistics)Metal-organic frameworkMaterials scienceChemical engineeringThermalChemistryAdsorptionNanotechnologyOrganic chemistryMeteorologyEngineeringPhysicsLinguisticsPhilosophyMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMembrane Separation and Gas Transport