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Recent progress in cathode interlayer materials for non‐fullerene organic solar cells

Nafees Ahmad, Huiqiong Zhou, Ping Fan, Guangxing Liang

2021EcoMat121 citationsDOIOpen Access PDF

Abstract

Abstract Non‐fullerene acceptors are currently a hot research area in the development of organic solar cells (OSCs). At present, the‐state‐of‐the‐art power conversion efficiency (PCE) of non‐fullerene organic solar cells (NF‐OSCs) with single and multiple‐junction has surpassed 18% and 19%, respectively. The cathode interlayer (CIL) plays a significant role in the improvement of PCE and the stability of OSCs. Recently, a large number of CIL materials have been employed in OSCs. This review summarizes the recent progress of CIL materials and systematically describes their impact on the device efficiency and stability in single‐junction NF‐OSCs. Firstly, the functions, key requirements, and distinctive features of CILs when used in NF‐OSCs are summarized. Afterward, some big families of materials including metal oxides, metal salts/complexes, small molecules, polymers, composites/hybrids are presented as CIL for NF‐OSCs. Finally, the scale‐up techniques, conclusion, and future challenges regarding CIL in NF‐OSCs are elucidated. image

Topics & Concepts

Organic solar cellCathodeMaterials scienceFullereneNanotechnologyEnergy conversion efficiencyPolymerOptoelectronicsChemistryComposite materialOrganic chemistryPhysical chemistryOrganic Electronics and PhotovoltaicsConducting polymers and applicationsSemiconductor materials and interfaces