Balance between Fe<sup>IV</sup>–Ni<sup>IV</sup> synergy and Lattice Oxygen Contribution for Accelerating Water Oxidation
Chao Jing, Lili Li, Yi‐Ying Chin, Chih‐Wen Pao, Wei‐Hsiang Huang, Miaomiao Liu, Jing Zhou, Taotao Yuan, Xiangqi Zhou, Yifeng Wang, Chien‐Te Chen, Da‐Wei Li, Jian‐Qiang Wang, Zhiwei Hu, Linjuan Zhang
Abstract
High Resolution Image Download MS PowerPoint Slide Hydrogen obtained from electrochemical water splitting is the most promising clean energy carrier, which is hindered by the sluggish kinetics of the oxygen evolution reaction (OER). Thus, the development of an efficient OER electrocatalyst using nonprecious 3d transition elements is desirable. Multielement synergistic effect and lattice oxygen oxidation are two well-known mechanisms to enhance the OER activity of catalysts. The latter is generally related to the high valence state of 3d transition elements leading to structural destabilization under the OER condition. We have found that Al doping in nanosheet Ni–Fe hydroxide exhibits 2-fold advantage: (1) a strong enhanced OER activity from 277 mV to 238 mV at 10 mA cm –2 as the Ni valence state increases from Ni 3.58+ to Ni 3.79+ observed from in situ X-ray absorption spectra. (2) Operational stability is strengthened, while weakness is expected since the increased Ni IV content with 3d 8 L 2 (L denotes O 2p hole) would lead to structural instability. This contradiction is attributed to a reduced lattice oxygen contribution to the OER upon Al doping, as verified through in situ Raman spectroscopy, while the enhanced OER activity is interpreted as an enormous gain in exchange energy of Fe IV –Ni IV, facilitated by their intersite hopping. This study reveals a mechanism of Fe–Ni synergy effect to enhance OER activity and simultaneously to strengthen operational stability by suppressing the contribution of lattice oxygen.