Amorphous Copper‐modified Gold Interface Promotes Selective CO<sub>2</sub> Electroreduction to CO
Peng Zhan, Shuai Yang, Mengen Chu, Qian Zhu, Yan Zhuang, Cong Ren, Ziyi Chen, Lu Lu, Peiyong Qin
Abstract
Abstract Electroreduction of CO 2 into valuable chemicals exhibits promising application potentials. Herein, a kind of nano‐porous AuCu foam which possesses amorphous copper (Cu)‐modified gold (Au) interface was designed for highly selective electroreduction CO 2 into CO. As‐obtained Au 0.95 Cu 0.05 foam exhibits a Faradaic efficiency (FE) of 99.5 % for CO with a current density of 31.3 mA cm −2 . Compared with other Au‐based electrocatalysts, Au 0.95 Cu 0.05 foam shows a lower overpotential of 240 mV. The improvements in activity and selectivity of the AuCu foam might be attributed to the synergistic effect between the highly dispersed amorphous Cu and the matrix of Au. Detailed characterization indicates that the twisty nanowire morphology imparts multiple reactive sites on the electrode surface. The study demonstrates that amorphous Cu on the AuCu foam surface can boost CO 2 activation by modifying the surface geometry and electronic structure. This finding provides a new strategy of modifying the metal interface to construct electrocatalyst.