Effect of low concentration electrolytes on the formation and corrosion resistance of PEO coatings on AM50 magnesium alloy
Peng Xie, Carsten Blawert, Maria Serdechnova, Natalia Konchakova, Tatsiana Shulha, Ting Wu, Mikhail L. Zheludkevich
Abstract
In this paper, the formation process, morphology, and electrochemical performance of PEO coatings on AM50 magnesium alloy prepared in low concentration phosphate, aluminate, and phosphate-aluminate electrolytes were systematically studied. The results show that the coatings prepared from the phosphate electrolytes have a higher thickness and better corrosion resistance properties compared to the other electrolytes. The coatings prepared from low concentration phosphate-aluminate mixed electrolytes have slightly thinner thickness, a similar coating structure and an order of magnitude lower value of electrochemical impedance compared with phosphate electrolyte coatings. The Coatings prepared from low concentration aluminate electrolytes have the lowest thickness and the worst corrosion resistance properties which gets close to corrosion behavior of the bare AM50 under the same test conditions. Considering application, coatings prepared from single low concentration phosphate electrolytes and low concentration phosphate-aluminate electrolytes have greater potential than single low concentration aluminate coatings. However, reducing the electrolyte concentrations of coating forming ions too much has negative influence on the coating growth rate.